This is caused by high humidity and difference in temperature from inside to outside. So in winter when you have the heater on, there is a reaction when the inside of the upvc is heated and the outside is cooled and causes condensation to build up. Very similar to when you are in a car and there is humid cold weather. The black spots are very possibly a fungus growing as a result of the high humidity. You need to introduce fresh air into the house possible with a small inlet fan.
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