First turn off sync Mail accounts in iTunes and remove the mail accounts in the iphone, then with openss from my windows WinSCP set permissions /var/mobile/Library in the folder "Mail" to 777, now itunes can sync yours mail accounts, then go to iPhone open icon Settings into then go to "Mail, Contacts, Calandars" option and go Accounts "xxxx" -> SMTP here set the username and password for ur account and delete other SMTP Servers and if you have another account with other server you just add. and add /exchange to the end of my server name (mail.server.com/exchange) then it worked perfectly. You also need to make sure that your smtp port on the exchange server matches the iphone's smtp port and that your firewall won't block it.
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