Will the MU21CV radio's work
Short answer, maybe. It depends on whether you have a 14 channel or a 30 channel Talk-About. The Motorola Talk-Abouts operate on the FRS frequencies (14 channel) or FRS & GMRS frequencies (30 channel). The MU21CV does cover a few of the GMRS frequencies. (see bold numbers)
GMRS Frequencies
462.500, 462.575, 462.600, 462.625, 462.650, 462.675, 462.700, 462.725, 467.550, 467.575, 467.600, 467.625, 467.650, 467.675, 467.700 & 467.725
FRS Frequencies
462.5625, 462.5875, 462.6125, 462.6375, 462.6625, 462.6875, 462.7125, 467.5625, 467.5875, 467.6125, 467.6375, 467.6625, 467.6875, 467.7125
MU21CV Frequencies
464.500, 464.550, 467.7625, 467.8125, 467.850, 467.875, 467.900, 467.925, 462.575, 462.625, 462.675, 464.325, 464.825, 469.2625, 469.500, 469.550, 462.7625, 462.7875, 462.8125, 462.8375, 462.8625, 462.8875, 462.9125, 464.4875