All Air Conditioning blows our the defrost vents

Some thing you could look at would be this. The control is usually fed by a vacuum line or small hose thats is connected to your intake manifold.
With a cold engine,look for a skinny vacuum hose that runs from the intake toward the fire wall . It should be going inside the cab and connecting to the A/C vent control.Some times the hose becomes disconnected or splits or cracks due to heat under the hood.
Thats usually the trouble.
I hope this helps you.